Physical Chemistry III
Structure of Matter

Contents  it is more important than any introduction
 

I.   Revolution In Physics  

II.  Basic Features of Quantum Mechanics

III. Simple Applications

IV. Corner Stone of Chemistry: Hydrogen Atom and Rotation

V.  The Periodical System of Elements

VI. Molecular spectra


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Literature
Exercises
Praktikumsversuch

I. Revolution in physics
and their mathematical description
Classical Ideas and Conceptions
Black Body Irradiation   The Planck's Radiation Formula Derivation Using the Einstein's Coefficients
Quanta
The Matter is also the wave, said de Broglie
The Uncertainty Principle
Wavepacket  

 
II. Basic Features of Quantum Mechanics
mathematical treatment
Experiments with Waves, Balls and Electrons  
Three Basic Principles of Quantum Mechanics
Chemical Reaction Control without Energy
The Schroedinger equation
 
 

 
III. Simple Applications
and mathematical application
From Butadiene to Polyene
Degeneracy and Symmetry
The Tunneling Phenomenon (Example Ammonia)
Summarize and explain (1) - Benzene  
Summarize and explain (2) - Molecular Hydrogen  
Simple molecular vibrations: harmonic oscillator:
 

IV. Corner Stone of Chemistry:  
Hydrogen atom
and rotation
The Hydrogen Atom
The kinetic moment ²
The Energy States and Radial Wavefunction R(r) of Hydrogen Atom
Eigenvalues of Kinetic Moment Calculation
The Rotational Energy
The Rotational Eigenfunctions
Wavefunction Illustrations y = R(r) Y(J,j)
Spin Eigenvalues and Eigenfunctions
Nomenclature of Atomic States
Addition of Kinetic Moments
Fine, Hyperfine and the Kinetic Moment of Photon


V. The Periodical System of Elements

  1. Russel-Saunders- vs. jj-Coupling
  2. Pauli Principle and Hunds Rule
  3. From H To B
  4. From C To Ne
  5. From Na Till the Very End
  6. Configurations of All Elements
  7. How Can We Get the Roentgen Radiation?

VI. Molecular spectra
  1. Introduction
  2. Optical Transitions
  3. Rotational Spectra
    1.  Spherical Top
    2.  Symmetric Top
    3.  Linear Top
    4. Asymmetric Top
    5.  Moving Rotator
    6.  Selection Rules For Pure Rotational Transitions
  4. Vibrational and-Rotational Spectra
  5. Electronic Spectra


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