Zeeman Effect

The ordinary Zeeman Effect

The kinetic moment vector  j and magnetic moment µ_j rotate together around field direction B. The additional atomic energy of atom is then as follows: 

Here we have (2j + 1)-fold degeneracy which splits the term into 2j + 1 components. They are energy-wise equidistant. 

The separation of two components with Δm_j  = 1 is given by:

If we neglect spin and take only orbital magnetism then it will be g_j = 1.

We will have the selection rule for optical transitions:

We will have only three lines regardless of the amount of term components in the quantum theory: the ordinary Zeeman-Triplet. 
 

Fig. 1: Ordinary Zeeman effect. The splitting of line                   l = 6438 Å of neutral Cd-Atoms, transition 1P1 - 1D2, is then splitted into 3 components when applying magnetic field. Transitions with Δmj = 0 is called π-, transitions with   Δmj = ±1 σ-transitions. The quantum number J is written using capital letter here since we're talking about many-electron atom here.

Figure 1 shows the splitting picture for Cadmium line. The spins of both electrons are antiparallel and they compensate each other giving total spin S = 0. Transitions between components with different terms (for instance ¹P₁ or ¹D₂ in Fig.1) with the same Δm_j happen since the splitting is high (we're talking about pure orbital magnetism in both cases). The unbiased line corresponds to transitions      Δm = 0 and the off-center lines correspond to transitions Δm = ±1. They are circular polarized light. 

If we will base upon the conservation law for total kinetic moment of electron and light quanta together then it follows from the polarization behavior during the Zeeman effect that the light quanta have kinetic moment 1 · h.
 
 

The inordinary Zeeman Effect

We are talking about the inordinary Zeeman effect whether the kinetic and magnetic moments of both terms (between which there will be optical transition) is described not only by quantum numbers s or l (S or L) but rather by both of them simultaneously. This is more general case. 

When we have the inordinary Zeeman effect both optical terms taking place in the transition will have different g-factors. They are determined for total kinetic moments  j and therefore they are referred to as g_j-factors. The term splitting in the ground and excited states is quite big that's why the transition to ordinary Zeeman effect differs. The calculation of g_j-factors finally gives the following: 

Let's try to describe the inordinary Zeeman effect using example of  NaD lines (Fig. 2).

For three terms between which there are transitions of Na atoms D-lines namely ¹S_½, ²P_½ and ²P_3/2 there are magnetic moments in the field direction

And the magnetic energy of state is given again by:

The number of splitting components in the field is given by m_j and it's equal again to 2j+1. Nevertheless the separation between components with different m_j - the so-called Zeeman components - isn't more for higher terms. It depends on quantum numbers l, s and j:

Fig. 2:  The inordinary Zeeman effect. The line splitting     D1 and D2 of neutral Na atoms, transitions 2S½-2P½ and 2S½-2P3/2 give rise to 4 and 6 components in the magnetic field, correspondingly.

Experiments give g_j = 2 for the ground state ²S_½, g_j = ²/₃ for the state ²P_½ and ⁴/₃ for the state ²P_3/2 which were obtained by using formula for g_j. The selection rule for optical transitions is given again by   Δm_j = 0, ± 1. Here we obtain 10 lines which are shown on fig. 2.

The meaning of Zeeman effect lies basically in the empirical term analysis. The term splitting depends unambiguously on the quantum numbers l, s and j and L, S and J for many-electron atoms, correspondingly. Therefore they can be obtained from empirical measurements of Zeeman effect. 

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