- Molecular Spectroscopy -
Discussion Fr 04.11.2005 at 12:15, HR 30.1
Home work 1
Exercise 1: De Broglie wavelength
Consider a He gas at room temperature. As you know, helium is a single-atomic gas. The mean kinetic energy of each atom at the temperature T is E = 3/2 kT, where k is the Boltzmann constant.
a. Calculate the mean velocity of a helium atom, v in cm/s. Calculate the de Broglie wavelength λ in cm which corresponds to this velocity. Assuming the normal atmospheric pressure, calculate the mean distance between helium atoms d and compare this distance with the de Broglie wavelength. One may expect that the quantum effects can be important if l ³ d, otherwise, the classical description should be used. Which case is realized for the helium gas? What one should expect decreasing/increasing the temperature and the gas pressure?
b. The density of liquid helium is 0.15 g/cm3. Following the
previous problem compare the mean distance between the atoms d with the
de Broglie wavelength λ
at the temperature T = 0.01K.
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