Determination of Energy Levels and Coefficients


The secular equations

are transformed to obtain an equation with coefficient cA on the left and cB on the right side. If we divide we find that

or the quadratic equation

which is equivalent to α−E1/2 = ±(β−E1/2S). The solutions for E1 and E2 are

If we insert the solution E = (&alpha+&beta)/(S+1) into the secular equation, we get

If this equation is multiplied with 1+S we get

which is true for

In the same way, we insert E = (&alpha-&beta)/(S-1) into the secular equation and obtain a second pair of coefficients


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