Distinguishable and Identical Particles
The probability P(θ) of detecting a particle at angle θ depends on the dispersion amplitude f(θ) for
distinguishable particles: non distinguishable particles:
Pd(q)  =  |f(θ)|2 + |f(p-q)|2

An example here are nitrogen and hydrogen atoms. 
The detector should be sensitive to N and O atoms in order to distinguish between them. Though we can't distinguish N and O atoms it's possible in principle! Hence the probabilities and amplitudes do not sum together.

Pi(θ)  =  |f(θ) + f(p-q)|2

An example is   α-particles (helium nuclei, He++
Because there are two possibilities to register α-particles by our detector (namely the particle is dispersed on angles θ or p - q ) we can't distinguish between the incident particle and the target particle.

For dispersion angle θ = π/2 it's obviously f(θ)  =  f(p - q), i.e.:
  Pd(θ=π/2) = ½f(θ=π/2)½2 +½f(θ=π/2)½2
=  2½f(θ=π/2)½
Pi(θ=π/2) =½f(π/2) + f(π/2)½2
     = 4½f(π/2)½2

Unfortunately, it's more complicated if we observe dispersion of identical electrons. The following will result in this case:
 

  Pi(Elektronen) = ½f(θ) − f(p-q)½
And also
  for θ = π/2:    Pi (π/2) = 0

We previously thought that electrons are identical. Scientists tried dilligently to find any characteristic of electrons that would help them distinguish between two different electrons. The internal characteristic that they found is called Spin! (Stern-Gerlach Experiment). We now know that there are two "sorts" of electron, i.e. spin can take only two states which we will designate as spin up and spin down. Electrons with differing spins have the same features in diffraction experiment, i.e. there is no special identification characteristic with which one can identify different electron and therefore it's necessary:

Pi = ½f(θ) − f(p-q)½2.

If a spin up electron collides with a spin down electron,the particles are distinguishable and we can write:

Pd = ½f(θ)½2+½f(p-q)½2

An electron has spin s = 1/2 (both projections are possible ms = +1/2 and ms = -1/2 for spin up and spin down). Spin values can vary for other particles but it's always a multiple of 1/2. Therefore, all particles are divided into 2 classes:

Bose particles (integer spin):    f(θ) + f(p - q)     [α-particles, photons]
Fermi particles (half-integer spin):    f(θ) − f(p - q)      [electrons, muons]



If we first have a look at two Fermi particles going in one direction then they have dispersion amplitudes    f(θ1) and f(θ2). In order to obtain the Fermi particle probability one should subtract two dispersion amplitudes from each other:

Pi  = ½f(θ1) − f(θ2)½2

If both particles move in the same direction then it should be θ1 = θ2 or finally
 

  Pi  =  0  !!!

Hence two electrons with the same spin can't be in the same state. This is the well-known Pauli exclusion principle (Wolfgang Pauli).

We will see the concept of electron spin later when we study atomic and molecular spectroscopy. However, we now return again to the double slit experiment in order to describe sudden behavior of a particle using more comprehensive mathematics. Moreover we will again usestrange angle brackets and wavefunctions.

The Stern-Gerlach experiment schematic layout: the atomic beam comes through a homogeneous magnetic field. One observes fragmentation of the incident beam into 2 components which are designated as spin up and spin down. We observe a uniformly filled area (as it is shown on the left part of this figure).

Auf diesem Webangebot gilt die Datenschutzerklärung der TU Braunschweig mit Ausnahme der Abschnitte VI, VII und VIII.